You'd have to take a look at the 7.62X39 round side by side next to a .223 round.
The 7.62X39 is shorter, actually, but the main thing is how it tapers down. It is fat at the headstamp area and skinny at the shoulders. so when you get a bunch of them all lined up or stacked up against each other they want to form a semi-circle...or just some part of a circle.
Now, I haven't done it myself, but I am willing to give it a try.
They say if you get more than 10 of the 7.62X39 rounds into a normal AR15/.223 mag, all that stacking and tapered-ness makes the rounds jam or the follower tilt so much it doesn't push the rounds up to the top in order to get stripped off by the bolt.